Does anyone know how enzymes help us absorb vitamins better?

I am coming up on 2 years post op. I saw an informercial the other day for a new product which I cannot remember the name of, but they were saying how important enzymes are to help us metabolize our vitamins. I am having a particularly hard time with my arthritis and it is also supposed to help. The same doctor sells CALMAX which is a liquid form of calcium which I have been tempted to try, but have not found anyone who has. Can anyone enlighten me?

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